Liquid-liquid extraction separation of iron(III) with 2-ethyl hexyl phosphonic acid mono 2-ethyl hexyl ester

Liquid-liquid extraction separation of iron(III) with 2-ethyl hexyl phosphonic acid mono 2-ethyl hexyl ester (PC-88A) in toluene has been studied. Quantitative extraction of iron(III) with 5 x 10(-3) M PC-88A in toluene is observed in the pH range 0.75-2.5. From the extracted complex species in the organic phase iron(III) was stripped with 1-4 M HNO3, 1.5-4 M H2SO4 and 1.5-4 M HCl, and later determined spectrophotometrically by thiocyanate method. Separation of iron(III) was carried out with some of the first transition metals in binary and multicomponent mixtures. This method was extended for the determination of iron in real samples. (C) 1997 Elsevier Science B.V.