Theory of acyclic chemical networks and enumeration of polyenoids via two-dimensional chirality

被引：8

作者：

Yeh, CY

机构：

[1] Department of Anesthesiology, University of Utah School of Medicine, Salt Lake City

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 39期

关键词：

D O I：

10.1021/jp961433k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Procedure for constructing acyclic chemical networks is delineated through the example of polyenoids, CNHN+2. Chirality in two-dimensional space is introduced to enumerate polyenoids. Cis-trans dichotomies, each arising from a 2D chiral center, are stacked to form stereoisomers. Redundancy caused by rotating the molecular plane in 3D space is eliminated to obtain the net count of isomers.

引用

页码：15800 / 15804

页数：5

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