Chirality-sensing supramolecular systems

被引:851
作者
Hembury, Guy A. [1 ,2 ,3 ]
Borovkov, Victor V. [1 ,2 ]
Inoue, Yoshihisa [1 ,2 ]
机构
[1] Osaka Univ, Japan Sci & Technol Agcy, Suita, Osaka 5650871, Japan
[2] Osaka Univ, Dept Appl Chem, Suita, Osaka 5650871, Japan
[3] Univ Manchester, Mol Mat Ctr, Manchester M13 9PL, Lancs, England
关键词
D O I
10.1021/cr050005k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An overview about the supramolecular systems for chirality-sensing regarding its key areas and some examples is given. There were five distinct aspects of discussions to be considered. First, the different manifestations of (supra)-molecular chirality has been discussed. Second, some recent works particularly on the asymmetry induction and control in various host-guest assemblies and the enantiodiscrimination in host-guest systems. Third, a consideration will be given that will be dealing with the various external and internal modulating stimuli in a chirality. Fourth, the different branches of chirogenesis that will illustrate well the rational design of sophisticated supramolecular systems will be shown. Lastly, the current limitations and some possible approaches to solve such problems will be discussed.
引用
收藏
页码:1 / 73
页数:73
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