Photoassisted production of O2-• and H2 in aqueous medium stimulated by polythiophene in ZSM-5 zeolite channels

被引：10

作者：

Cík, G ^{[1
]}

Sersen, F

Bumbálová, A

机构：

[1] Slovak Univ Technol Bratislava, Dept Environm Sci, Bratislava 81237, Slovakia

[2] Comenius Univ, Fac Nat Sci, Inst Chem, Bratislava 84215, Slovakia

[3] Comenius Univ, Fac Pharm, Dept Pharmaceut Anal & Nucl Pharm, Bratislava 83232, Slovakia

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1999年 / 64卷 / 01期

关键词：

ZSM-5; zeolites; polythiophenes; reactive oxygen species; water photoreduction; water photolysis; photochemistry;

D O I：

10.1135/cccc19990149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of reactive oxygen species due to irradiation by a visible light of the polythiophene deposited in ZSM-5 zeolite channels in aqueous medium has been studied. Polymerization of thiophene was carried out in zeolite channels after the ion-exchange reaction of Na+ for Fe3+. By means of EPR spectroscopy, the temporarily generated O-1(2) in irradiated aqueous medium was proved. The formation of O-2(-.) was confirmed by the reduction of Fe3+-cytochrome c. Irradiation led to the water reduction to hydrogen.

引用

页码：149 / 156

页数：8

共 17 条

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