Swallowtail bacteriochlorins.: Lipophilic absorbers for the near-infrared

被引：34

作者：

Borbas, K. Eszter ^{[1
]}

Ruzie, Christian ^{[1
]}

Lindsey, Jonathan S. ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 10期

关键词：

D O I：

10.1021/ol800436u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bacteriochlorins absorb strongly in the near-infrared spectral region and hence are ideally suited for diverse photomedical applications, yet naturally occurring bacteriochlorins have limited stability and synthetic malleability. A de novo route has been exploited to prepare synthetic bacteriochlorins that bear a geminal dimethyl group in each pyrroline ring for stability and a symmetrically branched 1,5-dimethoxypentyl group attached to each pyrrole ring for solubility in lipophilic media.

引用

页码：1931 / 1934

页数：4

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