In Situ X-Ray Study of Drying-Temperature Influence on the Structural Evolution of Bulk-Heterojunction Polymer-Fullerene Solar Cells Processed by Doctor-Blading

被引:93
作者
Sanyal, Monamie [2 ]
Schmidt-Hansberg, Benjamin [1 ]
Klein, Michael F. G. [3 ]
Colsmann, Alexander [3 ]
Munuera, Carmen [2 ]
Vorobiev, Alexei [4 ]
Lemmer, Uli [3 ]
Schabel, Wilhelm [1 ]
Dosch, Helmut [5 ]
Barrena, Esther [6 ]
机构
[1] Karlsruhe Inst Technol, Inst Therm Verfahrenstech Thin Film Technol, D-76131 Karlsruhe, Germany
[2] Max Planck Inst Met Res, D-70569 Stuttgart, Germany
[3] Karlsruhe Inst Technol, Lichttech Inst, D-76131 Karlsruhe, Germany
[4] European Synchrotron Radiat Facil, F-38043 Grenoble 9, France
[5] Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany
[6] ICMAB CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain
关键词
PHOTOVOLTAIC CELLS; POLY(3-HEXYLTHIOPHENE); MORPHOLOGY; ORGANIZATION; EFFICIENCY; MOBILITY; NETWORK;
D O I
10.1002/aenm.201100007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In situ X-ray measurements give insight into the effect of substrate temperature on the structural evolution of doctor-bladed P3HT:PCBM blends during the transition from wet to solid, report Benjamin Schmidt-Hansberg, Esther Barrena, and co-workers. Drying the active layer at lower temperature (10°C) leads to a better nanomorphology with a finer interpenetrating network, and may be an easy route for the optimization of the performance in doctor-bladed solar cells. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:363 / 367
页数:5
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