Gradient profile prediction in functionally graded materials processed by electrophoretic deposition

被引：37

作者：

Put, S ^{[1
]}

Vleugels, J ^{[1
]}

Van Der Biest, O ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Met & Mat Engn, MTM, B-3001 Louvain, Belgium

来源：

ACTA MATERIALIA | 2003年 / 51卷 / 20期

关键词：

modeling; electrophoretic deposition; functionally graded materials (FGM); ceramics;

D O I：

10.1016/S1359-6454(03)00463-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrophoretic deposition (EPD) allows the formation of plate-shaped binary functionally graded materials (FGM) by depositing from a powder suspension to which a second suspension is continuously added during the process. The deposition yield is described as a function of time and starting composition of both suspensions, resulting in a model of the EPD process that allows predicting the composition gradient in the green deposit as well as in the sintered material. The model presented enables calculation of the composition gradient in the FGM material from the starting composition of the suspensions, the EPD operating parameters and the powder-specific EPD characteristics. The powder-specific parameters, i.e. the effective charge, the electrophoretic mobility, the specific conductivity of the intermicellar liquid and the specific resistance of the deposit, incorporated in the model were experimentally determined from EPD of the individual homogeneous powder suspensions. The model was verified for the ZrO2-Al2O3 system by the actual preparation and analysis of two different FGM materials. Because of the excellent correlation between the predicted and the measured concentration profiles, the described model allows to precisely engineer and design the composition profile in FGM materials produced by EPD. (C) 2003 Acta Materialia Ltd Published by Elsevier Ltd. All rights reserved.

引用

页码：6303 / 6317

页数：15

共 26 条

[1]

Andrews J. M., 1969, P BR CERAM SOC, V12, P211

[2]

Avgustinik A. I., 1962, J APPL CHEM-USSR, V35, P2090

[3]

Biesheuvel PM, 1999, J AM CERAM SOC, V82, P1451, DOI 10.1111/j.1151-2916.1999.tb01939.x

[4] Colloidal processing of a mullite matrix material suitable for infiltrating woven fibre preforms using electrophoretic deposition [J].

Boccaccini, AR ;

Trusty, PA ;

Taplin, DMR ;

Ponton, CB .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1996, 16 (12) :1319-1327

[5] Role of ionic depletion in deposition during electrophoretic deposition [J].

De, D ;

Nicholson, PS .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (11) :3031-3036

[6]

FERRARI B, 1997, GRUPPO EDITORIALE FA, V1, P421

[7]

Hamaker H., 1940, T FARADAY SOC, V36, P279

[8]

HIRAI T, 1996, MAT SCI TECNOLOTY B, V17, P297

[9] SYNTHESIS OF A FUNCTIONALLY GRADIENT MATERIAL BASED ON C/C COMPOSITES USING AN ELECTRODEPOSITION METHOD [J].

KAWAI, C ;

WAKAMATSU, S .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1995, 14 (07) :467-469

[10] FGM RESEARCH ACTIVITIES IN EUROPE [J].

KAYSSER, WA ;

ILSCHNER, B .

MRS BULLETIN, 1995, 20 (01) :22-26

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