Changes in hydrologic properties of aquifer media due to chemical reactions: A review

被引:51
作者
Saripalli, KP [1 ]
Meyer, PD [1 ]
Bacon, DH [1 ]
Freedman, VL [1 ]
机构
[1] Pacific NW Natl Lab, Richland, WA 99352 USA
关键词
subsurface; precipitation; dissolution; ion exchange; porosity; permeability; formation damage; reactive transport modeling;
D O I
10.1080/20016491089244
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Hydrologic properties that govern fluid flow through the subsurface are porosity, permeability, relative permeability, fluid-fluid and fluid-solid interfacial areas, pore and particle size distributions, which may change due to dissolution/precipitation of minerals, fine particle release and capture, ion exchange, and clay swelling. Provided here is a review on the change of hydrologic properties in subsurface media due to chemical processes, and the modeling of such changes. Precipitation and dissolution processes affecting the hydrologic properties, their kinetics and the effect of hydrodynamic factors on such processes are discussed. Precipitation in carbonaceous, siliceous, alkaline and acidic environments, and the role of dissolution and clay swelling in formation damage are reviewed. Changes in properties of unsaturated and fractured media were also discussed. Traditionally, different approaches were used to model various physico-chemical processes and their effect on the hydrologic properties. A detailed review of these methods, including the geochemical equilibrium and kinetic models, chemical divide pathway models, flow and transport models, precipitation/dissolution wave theory, network models, porosity and permeability reduction models, is presented. Recommendations are provided for the assessment of changes in the hydrologic properties of subsurface media attributable to chemical reactions, and modeling flow and transport in their presence. Further, research needs on the changes in hydrologic properties and constitutive relationships among such properties in unsaturated media are identified.
引用
收藏
页码:311 / 349
页数:39
相关论文
共 97 条
[1]  
ALIAGA DA, 1992, 19765 SPE
[2]  
[Anonymous], APPL SCI RES A, DOI DOI 10.1007/BF02120318
[3]  
ARAQUEMARTINEZ, 1999, SPE ANN TECHN C EXH
[4]   A PHYSICOEMPIRICAL MODEL TO PREDICT THE SOIL-MOISTURE CHARACTERISTIC FROM PARTICLE-SIZE DISTRIBUTION AND BULK-DENSITY DATA [J].
ARYA, LM ;
PARIS, JF .
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 1981, 45 (06) :1023-1030
[5]  
Atkinson G., 1991, SPE INT S OILF CHEM
[6]  
Bacon D.H, 2000, SUBSURFACE TRANSPORT
[7]   Estimating interfacial areas for multi-fluid soil systems [J].
Bradford, SA ;
Leij, FJ .
JOURNAL OF CONTAMINANT HYDROLOGY, 1997, 27 (1-2) :83-105
[8]  
BROWNING FH, 1993, P 1993 SPE INT S OIL
[9]   MINERAL SEQUENCES IN PRECIPITATION DISSOLUTION WAVES [J].
BRYANT, SL ;
SCHECHTER, RS ;
LAKE, LW .
AICHE JOURNAL, 1987, 33 (08) :1271-1287
[10]  
BURDINE NT, 1953, T AM I MIN MET ENG, V198, P71