Enlarged cavitand-based coordination cages

被引：43

作者：

Cuminetti, N

Ebbing, MHK

Prados, P

de Mendoza, J

Dalcanale, E

机构：

[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

[2] Univ Autonoma Madrid, Dept Quim Organ, E-28039 Madrid, Spain

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 03期

关键词：

self-assembly; cage compounds; cavitands;

D O I：

10.1016/S0040-4039(00)01991-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new coordination cages 1a,b were prepared via metal-directed self-assembly of the tetrakis(benzonitrile) cavitands 2a,b with Pt(dppp)(CF3SO3)(2) Their large portals allow fast exchange on the NMR timescale of encapsulated counterions or guests with solvent molecules. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：527 / 530

页数：4

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