RETRACTED: Performance of modified montmorillonite clay in mercury adsorption process and thermodynamic studies (Retracted article. See vol. 14, pg. 1988, 2011)

被引:45
作者
Guerra, Denis L. [1 ]
Airoldi, Claudio [1 ]
Viana, Rubia Ribeiro [2 ]
机构
[1] Univ Estadual Campinas, Inst Quim, BR-13084971 Campinas, SP, Brazil
[2] Univ Fed Matogrosso, Ctr Recursos Minerais, Cuiaba, Brazil
基金
巴西圣保罗研究基金会;
关键词
montmorillonite; adsorption isotherms; mercury; calorimetry;
D O I
10.1016/j.inoche.2007.09.029
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The montmorillonite clay sample from amazon region, Par State, Brazil, was used for intercalation process with pyridine (P) and organofunctionalization with 3-aminopropyltriethoxysilane (APS). The montmorillonite-P/APS shows variation of d(001) values, by changing d(001) from 1.15 to 2.10 mm. The original and modified samples were used for mercury cation adsorption from aqueous solution at room temperature and pH 6.0. The energetic effect caused by mercury cation adsorption was deter-mined though calorimetric titration at the solid-liquid interface and gave a net thermal effect that enabled the calculation of the exothermic values and the equilibrium constant. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:20 / 23
页数:4
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