Structural isomers of M(dca)2 molecule-based magnets.: Crystal structure of tetrahedrally coordinated sheet-like β-Zn(dca)2 and β-Co/Zn(dca)2, and the octahedrally coordinated rutile-like α-Co(dca)2, where dca- = dicyanamide, N(CN)2-, and magnetism of β-Co(dca)2

被引：154

作者：

Jensen, P ^{[1
]}

Batten, SR ^{[1
]}

Fallon, GD ^{[1
]}

Moubaraki, B ^{[1
]}

Murray, KS ^{[1
]}

Price, DJ ^{[1
]}

机构：

[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 02期

关键词：

D O I：

10.1039/a808777f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

beta-Zn(dca)(2) and 0.12% Co(II) doped beta-Zn(dca)(2) contain tetrahedrally coordinated metal ions within a corrugated sheet network structure [dca = dicyanamide, N(CN)(2)(-)], beta-Co(dca)(2) is a spin-canted antiferromagnet (T-N = 9 K), while the rutile-like octahedral alpha-form is a ferromagnet.

引用

页码：177 / 178

页数：2

共 6 条

[1] Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2- [J].