Synthesis and chiroptical properties of axially chiral, binaphthol-based oligomers

被引：29

作者：

Ng, MK ^{[1
]}

Chow, HF ^{[1
]}

Chan, TL ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,NT,HONG KONG

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 17期

关键词：

binaphthol; optical active oligomers; optical activity;

D O I：

10.1016/0040-4039(96)00478-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active, axially chiral binaphthol-based oligomers 2 to 4 were synthesized via Hay's coupling from the monomer 1. These oligomers exhibited moderate optical rotation enhancement but the effect quickly reaches a plateau with the tetramer 4. (C) 1996 Elsevier Science Ltd

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页码：2979 / 2982

页数：4

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