Electrocatalytic formal [2+2] cycloaddition reactions between anodically activated enyloxy benzene and Alkenes

被引：41

作者：

Arata, Michiko ^{[1
]}

Miura, Teppei ^{[1
]}

Chiba, Kazuhiro ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Bioorgan Chem Lab, Tokyo 1838509, Japan

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 21期

关键词：

D O I：

10.1021/ol7019845

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrocatalytic formal [2+2] cycloadditions between anodically activated enyloxy benzene and alkenes have been accomplished in a lithium perchlorate/nitromethane electrolyte solution. The enyloxy benzene moiety of these electrolytic substrates played an important role in the formation of a radical cation that could accept nucleophilic alkenes, followed by intramolecular electron transfer between the cyclobutane and phenyl ether moieties of the intermediates.

引用

页码：4347 / 4350

页数：4

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