Fullerene-porphyrin constructs

被引:486
作者
Boyd, PDW [1 ]
Reed, CA
机构
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
[2] Univ Auckland, Dept Chem, Auckland 92019, New Zealand
关键词
D O I
10.1021/ar040168f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene-porphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices.
引用
收藏
页码:235 / 242
页数:8
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