Silver nanofibers from the nanorods of one-dimensional organometallic coordination polymers

被引：42

作者：

Akhbari, Kamran ^{[1
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 11期

关键词：

SUPRAMOLECULAR ISOMERISM; COMPLEXES; FLUORESCENCE; BONDS; TRANSFORMATION; NETWORK; SIZE;

D O I：

10.1039/c002740e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 1D pencil shaped organometallic coordination polymer, [Ag-2(mu(5)-TPOAc)(2)](n) (1) [TPOAc- = triphenylacetate], has been synthesized and characterized and its structure was determined by X-ray crystallography. There are two types of Ag+ ions, which form strong eta(2) Ag2-C pi bonds, two weak eta(1) Ag1 center dot center dot center dot C pi interactions and strong Ag-Ag interactions, resulting in the formation of C-2 center dot center dot center dot Ag1O(3)Ag(2) and Ag2O(3)C(2)Ag(2) moieties with very interesting structures. In addition we prepared metal coordination nano-polymers (MCNPs) of compound 1 by ultrasonic process where pyrolysis of compound 1 nanorods, as a template, result in silver nanofibers.

引用

页码：3394 / 3396

页数：3

共 39 条

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