The first metal complexes of 3,3′-bi-1,2,4-oxadiazole:: A curiously ignored ligand

被引：27

作者：

Richardson, Chris ^{[1
]}

Steel, Peter J. ^{[1
]}

机构：

[1] Univ Canterbury, Coll Sci, Dept Chem, Christchurch 1, New Zealand

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 08期

关键词：

1,2,4-oxadiazole; palladium; silver; N ligands;

D O I：

10.1016/j.inoche.2007.04.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of 3,3'-bi-1,2,4-oxadiazole (1) reveals a planar centrosymmetric structure for this molecule in the solid state. It forms a mononuclear complex (3) with palladium(II) chloride, which is shown by X-ray crystallography to contain the ligand chelated through the two N4 nitrogens. The X-ray structure of the complex (5) with silver(l) nitrate shows a one-dimensional coordination polymer in which the ligand acts in a bridging mode, again with coordination through the N4 nitrogen atoms. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：884 / 887

页数：4

共 28 条

[1]

ADRIANOV VG, 1994, CHEM HETEROCYCL COMP, V30, P475

[2] Synthesis of (1,2,4-oxadiazole)palladium(II) complexes by [2+3] cycloaddition of nitrile oxides to organonitriles in the presence of PdCl2 [J].

Bokach, NA ;

Kukushkin, VY ;

Haukka, M ;

Pombeiro, AJL .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (05) :845-853

[3] A route to 1,2,4-oxadiazoles and their complexes via platinum-mediated 1,3-dipolar cycloaddition of nitrile oxides to organonitriles [J].

Bokach, NA ;

Khripoun, AV ;

Kukushkin, VY ;

Haukka, M ;

Pombeiro, AJL .

INORGANIC CHEMISTRY, 2003, 42 (03) :896-903

[4] Synthesis and X-ray crystal structures of cobalt and copper complexes of 1,3-bis(benzotriazolyl)propanes [J].

Borsting, P ;

Steel, PJ .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (02) :376-380

[5] Recent advances in supramolecular design and assembly of silver(I) coordination polymers [J].

Chen, CL ;

Kang, BS ;

Su, CY .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (01) :3-18

[6] Structural and electronic properties of the iron(II) and nickel(II) bis(ligand) complexes of 6-(5-methyl-1,2,4-oxadiazol-3-yl)-2,2′-bipyridine -: a terpyridine-based tridentate [J].

Childs, BJ ;

Craig, DC ;

Scudder, ML ;

Goodwin, HA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1999, 52 (07) :673-680

[7] Helices versus zigzag chains:: One-dimensional coordination polymers of AgI and bis(4-pyridyl)amine [J].

Cordes, David B. ;

Hanton, Lyall R. ;

Spicer, Mark D. .

INORGANIC CHEMISTRY, 2006, 45 (19) :7651-7664

[8] Syntheses of chelating tetrazole-containing ligands and studies of their palladium(II) and ruthenium(II) complexes [J].

Downard, AJ ;

Steel, PJ ;

Steenwijk, J .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1995, 48 (09) :1625-1642

[9] Chiral heterocyclic ligands. XIII. Synthesis and X-ray crystal structure of a chiral, unidirectional, silver coordination polymer [J].

Fitchett, CM ;

Steel, PJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (01) :19-21

[10] Solid state conformations of symmetrical aromatic biheterocycles: an X-ray crystallographic investigation [J].

Fitchett, CM ;

Richardson, C ;

Steel, PJ .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (03) :498-502

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