Synthesis and anion binding ability of metacyclophane-based cyclic thioureas

被引:27
作者
Tobe, Y [1 ]
Sasaki, S [1 ]
Mizuno, M [1 ]
Naemura, K [1 ]
机构
[1] Osaka Univ, Fac Engn Sci, Dept Chem, Osaka 5608531, Japan
关键词
D O I
10.1246/cl.1998.835
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cyclophanes having two thiourea groups were synthesized and their anion binding ability was examined by titration method using H-1-NMR spectroscopy. Strong and selective anion binding of the preorganized cyclic receptors was observed in the general order of H2O4. > CH3COO. > Cl-. > HSO4. > Br-..
引用
收藏
页码:835 / 836
页数:2
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