Oxidative addition of diferrocenyl dichalcogenides to [{Ru(eta(5)-C(5)Me(5))-(mu(3)-Cl)}(4)]. Syntheses, crystal structures and some reactivities of [{Ru(eta(5)-C(5)Me(5))Cl(mu-ER)}(2)] (E=S, Se or Te; R equals ferrocenyl)

被引：40

作者：

Matsuzaka, H

Qu, JP

Ogino, T

Nishio, M

Nishibayashi, Y

Ishii, Y

Uemura, S

Hidai, M

机构：

[1] UNIV TOKYO,GRAD SCH ENGN,DEPT CHEM & BIOTECHNOL,TOKYO 113,JAPAN

[2] KYOTO UNIV,GRAD SCH ENGN,DEPT ENERGY & HYDROCARBON CHEM,KYOTO 60601,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 22期

关键词：

D O I：

10.1039/dt9960004307

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [{Ru(eta(5)-C(5)Me(5))(mu(3)-Cl)}(4)] with 2 equivalents of REER (E = S, Se or Te; R = ferrocenyl) gave novel ferrocenylchalcogenolate-bridged diruthenium complexes [{Ru(eta(5)-C(5)Me(5))CI(mu-ER)}(2)] in good yields. Reduction of these by sodium amalgam in the presence of buta-1,3-diene afforded [{Ru(eta(5)-C(5)Me(5))(mu-ER)}(2)(mu-s-trans-eta(2): eta(2)'-CH2=CHCH=CH2)], whereas treatment with AgOSO2CF3 produced,the co-ordinatively unsaturated complexes [Cl(eta(5)-C(5)Me(5))Ru(mu-ER)(2)Ru(eta(5)-C(5)Me(5))][OSO2CF3]. The structures of five of the complexes have been defined by X-ray crystallography.

引用

页码：4307 / 4312

页数：6

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[1] PREPARATION OF NOVEL PLATINUM AND PALLADIUM COMPLEXES BY REACTION OF 1,1'-METALLOCENEDICHALCOGENOLS WITH TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) OR TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0) - THE IMPORTANT ROLE OF THE COORDINATING ABILITY OF THE METAL ATOM OF THE METALLOCENE IN PRODUCT FORMATIONH [J].