Electronic properties of three- and low-dimensional semiconducting materials with Pb halide and Sn halide units

被引:214
作者
Koutselas, IB [1 ]
Ducasse, L [1 ]
Papavassiliou, GC [1 ]
机构
[1] UNIV BORDEAUX 1,LAB PHYSICOCHIM THEOR,URA CNRS 503,F-33045 TALENCE,FRANCE
关键词
D O I
10.1088/0953-8984/8/9/012
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Band-structure calculations, semiempirical as well as ab initio, have been applied to study the electronic band gap of the new exotic natural low-dimensional MX systems (where M = Pb or Sn and X = I, Br or Cl). Moreover, variational calculations are employed to calculate the excitonic binding energies, whose amplification is due not only to the quantum confinement of the excitons but also to a dielectric enhancement effect. A single set of semiempirical parameters is sought to describe the materials; comparison of the calculations with experimental data shows this to be successful in the case of the PbI- and PbBr-containing compounds.
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页码:1217 / 1227
页数:11
相关论文
共 34 条
[1]  
Alvarez S., 1989, TABLE PARAMETERS EXT
[2]   EXCITONS AND BIEXCITONS IN SEMICONDUCTOR QUANTUM WIRES [J].
BANYAI, L ;
GALBRAITH, I ;
ELL, C ;
HAUG, H .
PHYSICAL REVIEW B, 1987, 36 (11) :6099-6104
[3]   SEMICONDUCTING CSSNBR3 [J].
BOSE, SK ;
SATPATHY, S ;
JEPSEN, O .
PHYSICAL REVIEW B, 1993, 47 (08) :4276-4280
[4]  
CHEMLA DS, 1993, PHYS TODAY JUN, P46
[5]  
DOVESI R, 1992, CRYSTAL 92 USER DOCU
[6]  
GIPPIUS NA, 1994, MATER RES SOC SYMP P, V328, P775
[7]   COULOMB INTERACTION AND EXCITONS IN A SUPERLATTICE [J].
GUSEINOV, RR .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1984, 125 (01) :237-243
[8]  
HANAMURA E, 1988, NATO ASI SERIES, V194
[9]   EXCITONS IN ANISOTROPIC SOLIDS - THE MODEL OF FRACTIONAL-DIMENSIONAL SPACE [J].
HE, XF .
PHYSICAL REVIEW B, 1991, 43 (03) :2063-2069
[10]   ELECTRONIC-STRUCTURE, PHOTOEMISSION SPECTRA, AND VACUUM ULTRAVIOLET OPTICAL-SPECTRA OF CSPBCL3 AND CSPBBR3 [J].
HEIDRICH, K ;
SCHAFER, W ;
SCHREIBER, M ;
SOCHTIG, J ;
TRENDEL, G ;
TREUSCH, J ;
GRANDKE, T ;
STOLZ, HJ .
PHYSICAL REVIEW B, 1981, 24 (10) :5642-5649