An impedance model for the estimation of water absorption in organic coatings. Part I: A linear dielectric mixture equation

被引:120
作者
Castela, AS [1 ]
Simoes, AM [1 ]
机构
[1] Univ Tecn Lisboa, Dept Chem Engn, Inst Super Tecn, P-1049001 Lisbon, Portugal
关键词
water uptake; organic coatings; electrochemical impedance;
D O I
10.1016/S0010-938X(03)00014-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A capacitance model for the estimation of water uptake in polymeric coatings is presented. The model is based upon a linear combination of the individual capacitances of the polymeric phase, the water and the air contained in the coating. Experimental comparison of the model with gravimetric data has revealed an improvement with respect to the classical equations. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1631 / 1646
页数:16
相关论文
共 16 条
[1]   WATER TRANSPORT IN ORGANIC COATINGS [J].
BELLUCCI, F ;
NICODEMO, L .
CORROSION, 1993, 49 (03) :235-247
[2]   ELECTRICAL MEASUREMENTS IN THE STUDY OF IMMERSED PAINT COATINGS ON METAL .1. COMPARISON BETWEEN CAPACITANCE AND GRAVIMETRIC METHODS OF ESTIMATING WATER-UPTAKE [J].
BRASHER, DM ;
KINGSBURY, AH .
JOURNAL OF APPLIED CHEMISTRY, 1954, 4 (02) :62-72
[3]  
CASTELA AS, 2000, 7 INT S EL METH CORR, P91
[4]   EIS evaluation of attached and free polymer films [J].
Castela, ASL ;
Simoes, AM ;
Ferreira, MGS .
PROGRESS IN ORGANIC COATINGS, 2000, 38 (01) :1-7
[5]   Monitoring degradation of single and multilayer organic coatings - I. Absorption and transport of water: Theoretical analysis and methods [J].
De Rosa, L ;
Monetta, T ;
Mitton, DB ;
Bellucci, F .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (11) :3830-3838
[6]   Organic coating capacitance measurement by EIS: ideal and actual trends [J].
Deflorian, F ;
Fedrizzi, L ;
Rossi, S ;
Bonora, PL .
ELECTROCHIMICA ACTA, 1999, 44 (24) :4243-4249
[7]   Influence of the photo-oxidative degradation on the water barrier and corrosion protection properties of polyester paints [J].
Deflorian, F ;
Fedrizzi, L ;
Bonora, PL .
CORROSION SCIENCE, 1996, 38 (10) :1697-1708
[8]  
Hartshorn L., 1937, J. Soc. Chem. Ind, V56, P266
[9]   THEORY OF DIELECTRIC-PROPERTIES OF HETEROGENEOUS SUBSTANCES APPLIED TO WATER IN A PAINT FILM [J].
LINDQVIST, SA .
CORROSION, 1985, 41 (02) :69-75
[10]   The sorption characteristics of epoxy coatings electrodeposited on steel during exposure to different corrosive agents [J].
MiskovicStankovic, VB ;
Drazic, DM ;
KacarevicPopovic, Z .
CORROSION SCIENCE, 1996, 38 (09) :1513-1523