Picosecond transient infrared spectrum of electronically excited trans-stilbene in acetonitrile and excited molecular structure

被引:6
作者
Okamoto, H [1 ]
机构
[1] Univ Tokyo, Sch Sci, Res Ctr Spectrochem, Bunkyo Ku, Tokyo 1130033, Japan
关键词
D O I
10.1246/cl.1998.1141
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The picosecond transient infrared spectrum of the lowest excited singlet (S-1) state of trans-stilbene in an acetonitrile solution has been recorded in the fingerprint region. Several absorption bands (absorption coefficients epsilon greater than or similar to 100) attributable to in-plane vibrations of the S-1 species have been observed. A minor contribution of a polarized structure to the S-1 state is suggested.
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页码:1141 / 1142
页数:2
相关论文
共 21 条
[1]   Vibrational analysis of stilbene and its isotopomers on the ground state potential energy surface [J].
Baranovic, G ;
Meic, Z ;
Maulitz, AH .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1998, 54 (08) :1017-1039
[2]  
CHIANG WY, 1994, J CHEM PHYS, V100, P8766
[3]   A RESONANCE RAMAN-STUDY OF SOLVENT EFFECTS ON THE EXCITED-STATE POTENTIAL SURFACE OF TRANS-STILBENE [J].
CI, XP ;
MYERS, AB .
CHEMICAL PHYSICS LETTERS, 1989, 158 (3-4) :263-270
[4]  
DOBKOWSKI J, 1994, NEW J CHEM, V18, P525
[5]   PICOSECOND TRANSIENT RAMAN-SPECTROSCOPY - THE PHOTO-ISOMERIZATION OF TRANS-STILBENE [J].
GUSTAFSON, TL ;
ROBERTS, DM ;
CHERNOFF, DA .
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (04) :1559-1564
[6]   OBSERVATION OF TRANSIENT RESONANCE RAMAN-SPECTRA OF THE S-1 STATE OF TRANS-STILBENE [J].
HAMAGUCHI, H ;
KATO, C ;
TASUMI, M .
CHEMICAL PHYSICS LETTERS, 1983, 100 (01) :3-7
[7]   EXCHANGE MODEL OF VIBRATIONAL DEPHASING IN S1 TRANS-STILBENE IN SOLUTION AND ITS POSSIBLE CORRELATION WITH THE ISOMERIZATION REACTION [J].
HAMAGUCHI, H ;
IWATA, K .
CHEMICAL PHYSICS LETTERS, 1993, 208 (5-6) :465-470
[8]  
Hamaguchi H., 1987, Vibrational spectra and structure. A series of Advances. Vol.16, P227
[9]   TRANSIENT RESONANCE RAMAN-SPECTRA AND VIBRATIONAL ASSIGNMENTS OF THE S1 STATE OF TRANS-STILBENE AND ITS DEUTERATED ANALOGS [J].
HAMAGUCHI, H ;
URANO, T ;
TASUMI, M .
CHEMICAL PHYSICS LETTERS, 1984, 106 (03) :153-156
[10]  
Hamaguchi HO, 1996, MOL PHYS, V89, P463, DOI 10.1080/00268979609482486