Utility of atom transfer radical polymerization for the preparation of poly(methyl methacrylate) beads in an aqueous suspension

被引：12

作者：

Bicak, N ^{[1
]}

Gazi, M ^{[1
]}

Tunca, U ^{[1
]}

Kucukkaya, I ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 06期

关键词：

methyl methacrylate; atom transfer radical polymerization (ATRP); suspension polymerization; hexylated triethylene tetramine ligand; GPC;

D O I：

10.1002/pola.11093

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The copper-mediated atom transfer radical polymerization of methyl methacrylate proceeds with first-order kinetics and controlled chain (300-600 mum) in growth to yield nearly spherical bead polymers aqueous suspensions when hexylated triethylenetetramine and poly(vinyl pyrrolidone) are used as the ligand and stabilizer, respectively.

引用

页码：1362 / +

页数：6

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