NMR characterization of allenyl-naphthol in the photochromic process of 3,3-diphenyl-[3H]-naphtho[2-1,b]pyran

被引：27

作者：

Delbaere, S ^{[1
]}

Vermeersch, G ^{[1
]}

机构：

[1] Univ Lille 2, UMR CNRS 8009, Fac Pharm, Phys Lab, F-59006 Lille, France

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2003年 / 159卷 / 03期

关键词：

photochromism; naphthopyrans; allenyl-naphthol; NMR spectroscopy;

D O I：

10.1016/S1010-6030(03)00191-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Allenyl-naphthol was produced after UV irradiation followed by visible light irradiation of 3,3-diphenyl-[3H]-naphtho[2-1,b]pyran (CH). Elucidation of its structure was obtained by 1D and 2D NMR spectroscopy. Kinetic study showed that its thermal bleaching followed a monoexponential decay, leading to an increase of concentration of TC merocyanine. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：227 / 232

页数：6

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