Molecular recognition of 2,6-diaminopyridine by platinum orotate complexes

被引：57

作者：

Burrows, AD

Mingos, DMP

White, AJP

Williams, DJ

机构：

[1] Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 01期

关键词：

D O I：

10.1039/dt9960000149

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of {[Pt(HL)(dppe)]. NC5H3(NH2)(2)-2,6}(2) [H(3)L = 2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylic acid, orotic acid, dppe = 1,2-bis(diphenylphosphino)ethane] has demonstrated that the in-built triple hydrogen-bonding functionality of the co-ordinated orotate is able to recognise at a molecular level 2,6-diaminopyridine, which has complementary hydrogen-bonding groups; this designed complementarity has produced a more efficient hydrogen-bonding arrangement than that possible in [Pt(HL)(dppe)] alone.

引用

页码：149 / 151

页数：3

共 14 条

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