From particle-assisted wetting to thin free-standing porous membranes

被引:58
作者
Xu, H
Goedel, WA [1 ]
机构
[1] Univ Ulm, D-89069 Ulm, Germany
[2] Dept Polymer Phys, D-67056 Ludwigshafen, Germany
关键词
nanostructures; particle-assisted wetting; polymers; porous membranes;
D O I
10.1002/anie.200351427
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Puncturing polymer membranes: Non-wetting organic liquids (see scheme; red) can form a mesoscopic wetting layer on a water surface (light blue), ifthey are mixed with suitable particles (dark blue). Photochemical cross-linking of the liquid in the mixed layer and transfer to metal grids or porous supports produces composite membranes. Subsequent removal of the particles yields free-standing porous membranes with uniform pore size and high porosity (see scheme).
引用
收藏
页码:4694 / 4696
页数:3
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