Orthogonally functionalized oligomers for controlled self-assembly

被引：51

作者：

Flatt, AK

Yao, YX

Maya, F

Tour, JM

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77251 USA

[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 05期

关键词：

D O I：

10.1021/jo035821b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occur after an in situ deprotection. Self-assembly data is reported for selected compounds to assess their efficacy in surface adhesion.

引用

页码：1752 / 1755

页数：4

共 19 条

[1] FORMATION OF MONOLAYER FILMS BY THE SPONTANEOUS ASSEMBLY OF ORGANIC THIOLS FROM SOLUTION ONTO GOLD
BAIN, CD
TROUGHTON, EB
TAO, YT
EVALL, J
WHITESIDES, GM
NUZZO, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 321 - 335
[2] Chemical and potential-assisted assembly of thiolacetyl-terminated oligo(phenylene ethynylene)s on gold surfaces
Cai, LT
Yao, YX
Yang, JP
Price, DW
Tour, JM
[J]. CHEMISTRY OF MATERIALS, 2002, 14 (07) : 2905 - 2909
[3] Synthesis of nitrile-terminated potential molecular electronic devices
Dirk, SM
Tour, JM
[J]. TETRAHEDRON, 2003, 59 (03) : 287 - 293
[4] A series of alpha,omega-dimercaptans
Hall, WP
Reid, EE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 : 1466 - 1468
[5] Effect of bond-length alternation in molecular wires
Kushmerick, JG
Holt, DB
Pollack, SK
Ratner, MA
Yang, JC
Schull, TL
Naciri, J
Moore, MH
Shashidhar, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (36) : 10654 - 10655
[6] Sequential catalytic synthesis of rod-like conjugated poly-ynes
Lavastre, O
Ollivier, L
Dixneuf, PH
Sibandhit, S
[J]. TETRAHEDRON, 1996, 52 (15) : 5495 - 5504
[7] Template synthesis of metal nanowires containing monolayer molecular junctions
Mbindyo, JKN
Mallouk, TE
Mattzela, JB
Kratochvilova, I
Razavi, B
Jackson, TN
Mayer, TS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (15) : 4020 - 4026
[8] Design and synthesis of potent nonpeptidic farnesyltransferase inhibitors based on a terphenyl scaffold
Ohkanda, J
Lockman, JW
Kothare, MA
Qian, YM
Blaskovich, MA
Sebti, SM
Hamilton, AD
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 2002, 45 (01) : 177 - 188
[9] Rapid syntheses of oligo(2,5-thiophene ethynylene)s with thioester termini: Potential molecular scale wires with alligator clips
Pearson, DL
Tour, JM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (05) : 1376 - 1387
[10] ADSORPTION OF ALKANENITRILES AND ALKANEDINITRILES ON GOLD AND COPPER
STEINER, UB
CASERI, WR
SUTER, UW
[J]. LANGMUIR, 1992, 8 (11) : 2771 - 2777

← 1 2 →