Molecular engineering of the internal charge transfer in thiophene-triphenylamine hybrid π-conjugated systems

被引：150

作者：

Leriche, Philippe ^{[1
]}

Frère, Pierre ^{[1
]}

Cravino, Antonio ^{[1
]}

Aleveque, Olivier ^{[1
]}

Roncali, Jean ^{[1
]}

机构：

[1] Univ Angers, Grp Syst Conjugues Lineaires, CIMMA, UMR CNRS 6200, F-49045 Angers, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 22期

关键词：

D O I：

10.1021/jo701390y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Introduction of electroaccepting groups at the periphery of triphenylamine-based derivatives leads to an internal charge-transfer band. Syntheses and spectroscopic, electrochemical, and theoretical studies of various derivatives which differ by the strength and the number of, electroacceptor groups are presented. These various results show that the ICT band and the acceptor/donor abilities of derivatives can be finely tuned.

引用

页码：8332 / 8336

页数：5

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