Variation of sol-gel synthesis parameters and their consequence for the surface area and structure of magnesium fluoride

被引：42

作者：

Wuttke, S. ^{[1
]}

Scholz, G. ^{[1
]}

Ruediger, S. ^{[1
]}

Kemnitz, E. ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2007年 / 17卷 / 47期

关键词：

D O I：

10.1039/b711855d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High surface area MgF2 was prepared by the sol-gel technique from magnesium alkoxides. The influence of different ratios of Mg(OCH3)(2) to HF, of different magnesium alkoxides, catalysts, solvents as well as different aging times was investigated. XRD, MAS-NMR, FT-IR, thermal analysis and elemental analysis were applied to study the structure, composition and thermal behaviour of the bulk materials. The determination of the surface properties was accomplished with N-2 and Ar adsorption-desorption isotherms.

引用

页码：4980 / 4988

页数：9

共 27 条

[1]

BRINKER CJ, 1990, SOL GEL SCI, V1, P47

[2] Adsorption of gases in multimolecular layers [J].