Sc3N@C80-ferrocene electron-donor/acceptor conjugates as promising materials for photovoltaic applications

被引：109

作者：

Pinzon, Julio R. ^{[5
]}

Plonska-Brzezinska, Marta E. ^{[5
]}

Cardona, Claudia M. ^{[5
]}

Athans, Andreas J. ^{[5
]}

Gayathri, S. Shankara ^{[1
,2
]}

Guldi, Dirk M. ^{[1
,2
]}

Herranz, M. Angeles ^{[3
]}

Martin, Nazario ^{[3
]}

Torres, Tomas ^{[4
]}

Echegoyen, Luis ^{[5
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

[2] Interdisciplinary Ctr Mol Mat, D-91058 Erlangen, Germany

[3] Univ Complutense, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

[4] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

[5] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 22期

关键词：

donor-acceptor systems; electrochemistry; electron transfer; fullerenes; nitrides;

D O I：

10.1002/anie.200800473

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intriguing materials for photovoltaics: The first trimetallic nitride endohedral metallofullerene covalently connected to a donor group is efficiently synthesized in a 1,3-dipolar cycloaddition reaction. Exclusive formation of the [5,6]-regioisomer in the isolated N-methyl-2-ferrocenyl-Ih-Sc 3N @C80-fulleropyrrolidine is confirmed by NMR spectroscopy and electrochemistry (see picture). (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4173 / 4176

页数：4

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