An S center dot center dot center dot S contact assembled tetranuclear copper(I) complex with sulfur-rich ligand, 4,5-ethylenedithio-1,3-dithiole-2-thione

被引:61
作者
Dai, J [1 ]
Munakata, M [1 ]
Wu, LP [1 ]
KurodaSowa, T [1 ]
Suenaga, Y [1 ]
机构
[1] KINKI UNIV,DEPT CHEM,HIGASHIOSAKA,OSAKA 577,JAPAN
关键词
crystal structures; copper complexes; sulfur ligand complexes; coordination polymers; CRYSTAL-STRUCTURE; M4X4; CORE; DMIT; SUPERCONDUCTORS; COORDINATION; MOLECULES; HALIDES; IODIDE;
D O I
10.1016/S0020-1693(96)05513-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A copper(I) complex with 4,5-ethylenedithio-1,3-dithiole-2-thione (C5H4S5), [Cu4I4(C5H4S5)(4)]infinity was synthesized and the molecular structure and packing were characterized crystallographically. The metal center is a stepped Cu4I4 core coordinated by two ligands C5H4S5 in different ways. One is bidentate coordinated through the thiocarbonyl group and the thioether group and the other is monodentate coordinated only through thiocarbonyl group. The Cu4I4 clusters are bridged by bidentate C5H4S5 molecules to form one-dimensional polymeric chains along the c-axis, and these chains form a three-dimensional network linked by interchain S ... S contacts. The shortest S ... S contact distance is 3.257(2) Angstrom. A crystal of the complex is triclinic with space group P (1) over bar, a=11.350(5) Angstrom, b=11.854(3) Angstrom, c=9.275(5) Angstrom, alpha=97.32(4)degrees,beta=112.35(4)degrees, gamma=67.67(2)degrees, V=1067.0(9) Angstrom(3), Z=2, R=0.034, R-w=0.051.
引用
收藏
页码:65 / 69
页数:5
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