Size-dependent surface-enhanced Raman scattering of Sodium Benzoate on silver nanoparticles

被引:36
作者
Badr, Y
Mahmoud, MA [1 ]
机构
[1] Zagazig Univ, Fac Sci, Dept Chem, Zagazig, Egypt
[2] Cairo Univ, Natl Inst Laser Enhanced Sci, Cairo, Egypt
关键词
Ag nanoparticles; SERS;
D O I
10.1016/j.molstruc.2005.04.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The absorption spectrum of silver nanoparticles (Ag NPs) with different size and the transmission electron microscopy (TEM) was recorded. Surface-enhanced Raman scattering (SERS) spectra of Sodium Benzoate (SB) adsorbed on Ag NPs with different particle size were studied. The carboxylic group bands were enhanced as the particle size decreases due to the chemisorption of SB on the Ag NPs through it in which the carboxyl group was perpendicular to the surface and the benzene ring parallel to the surface; the SB bands were enhanced as the coverage density of Ag NPs increased. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:187 / 192
页数:6
相关论文
共 22 条
  • [1] ANAVIND PK, 1981, SURF SCI, V110, P189
  • [2] AYORA MH, 1995, ANAL CHIM ACTA, V355, P15
  • [3] BADR Y, IN PRESS J PHYS CH B
  • [4] Chang R. K., 1981, SURFACE ENHANCED RAM
  • [5] EFFECT OF SILVER-NANOPARTICLE AGGREGATION AN SURFACE-ENHANCED RAMAN-SCATTERING FROM BENZOIC-ACID
    CHEN, MC
    TSAI, SD
    CHEN, MR
    OU, SY
    LI, WH
    LEE, KC
    [J]. PHYSICAL REVIEW B, 1995, 51 (07): : 4507 - 4515
  • [6] Some interesting properties of metals confined in time and nanometer space of different shapes
    El-Sayed, MA
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 257 - 264
  • [7] GABALIN LM, 1995, ANAL CHIM ACTA, V310, P337
  • [8] SURFACE-ENHANCED RAMAN-SCATTERING ON SILVER-COATED TEFLON SPHERE SUBSTRATES
    GOUDONNET, JP
    BEGUN, GM
    ARAKAWA, ET
    [J]. CHEMICAL PHYSICS LETTERS, 1982, 92 (02) : 197 - 201
  • [9] HAYASHI S, 1984, JPN J APPL PHYS, V28, P1444
  • [10] RAMAN-SPECTROSCOPY OF 4-(METHYLTHIO)BENZOIC ACID ADSORBED ON SILVER SURFACES
    KWON, YJ
    LEE, SB
    KIM, K
    KIM, MS
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1994, 318 : 25 - 35