Reaction of platinum(II) derivatives with 1-hydroxyalkyl-3,5-dimethylpyrazole ligands.: Cleavage of the N(pz)-C(sp3) bond.: X-ray crystal structure of cis-[PtCl2(HL2)2] (HL2=1-(2-hydroxyethyl)-3,5-dimethylpyrazole) and trans-[PtCl2(dmpz)2] (dmpz=3,5-dimethylpyrazole)

被引：46

作者：

Boixassa, A

Pons, J ^{[1
]}

Solans, X

Font-Bardia, M

Ros, J

机构：

[1] Univ Autonoma Barcelona, Fac Ciencies, Unitat Quim Inorgan, Dept Quim, E-08193 Barcelona, Spain

[2] Univ Barcelona, E-08028 Barcelona, Spain

来源：

INORGANICA CHIMICA ACTA | 2003年 / 355卷

关键词：

platinum complexes; pyrazole complexes; alcohol ligand complexes;

D O I：

10.1016/S0020-1693(03)00346-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of 1-hydroxymethyl-3,5-dimethylpyrazole (HL1) and 1-(2-hydroxyethyl)-3,5-dimethylpyrazole (HL2) with several platinum starting materials ([PtCl2(CH3CN)(2)], cis- and trans -[PtCl2(PhCN)(2)], PtCl2 and K2PtCl4) under different conditions have been examined and compared with those obtained from the reactions with Pd(II). cis and trans Pt(H) adducts are obtained in a different ratio depending on the metallic starting complex. The reaction of HL1 with any of the Pt(II) complexes differs from that with Pd(H) and also from the equivalent reaction of HL2 with Pt(II). This reaction implies the rupture of the ligand: the cleavage of the N(pz) -C(sp(3)) bond leads to [PtCl2(dmpz)(2)] (dmpz = 3,5-dimethylpyrazole). For comparison, the direct reaction of dmpz with Pt(H) has also been studied. The crystal structure of Cis-[PtCl2(HL2)(2)] and trans-[PtCl2(dMPZ)(2)] are here reported. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：254 / 263

页数：10

共 37 条

[1] Synthesis and characterisation of palladium compounds with new polyetherpyrazole ligands [J].