Bis(μ-5-sulfonatosalicylato)bis[bis(1,10-phen-anthroline)cadmium(II)] monohydrate

被引:5
作者
Fan, SR
Xiao, HP
Zhu, LG [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Wenzhou Normal Coll, Sch Chem & Mat Sci, Wenzhou 325027, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词
D O I
10.1107/S1600536805039437
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cd-2(C7H4O6S)(2)(C12H8N2)(4)] (.) H2O, the Cd-II atoms are bridged by two 5-sulfonatosalicylate dianions, forming a centrosymmetric dinuclear complex. Each Cd atom is coordinated by four N atoms from two 1,10-phenanthroline molecules and two O atoms from two 5-sulfonatosalicylate ligands in a distorted octahedral environment. A strong pi-pi stacking interaction occurs between 1,10-phenanthroline ligands from neighboring dimers. Extensive hydrogen bonds give rise to a two-dimensional network and enhance the stability of the crystal packing.
引用
收藏
页码:M18 / M20
页数:3
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