Infrared spectra of OMCO (M = Cr-Ni), OMCO- (M = Cr-Cu), and MCO2- (M = Co-Cu) in solid argon

被引：57

作者：

Zhou, MF ^{[1
]}

Liang, BY ^{[1
]}

Andrews, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22901 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1999年 / 103卷 / 13期

关键词：

D O I：

10.1021/jp984439d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser-ablated late transition metal atoms Cr through Ni react with CO2 molecules to give the insertion products OMCO, which have been isolated in solid argon. The insertion OMCO- molecular anions (Cr through Cu) were formed by electron capture and/or reaction with CO2-, and the addition MCO2- anions (M = Co, Ni, Cu) were produced by direct react:ion with CO2-. The excellent agreement between the observed frequencies and isotopic frequency ratios with those calculated by density functional theory supports these assignments.

引用

页码：2013 / 2023

页数：11

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