One-dimensional quantum transport in lead phthalocyanine nanostructures

被引:9
作者
Poklonski, NA [1 ]
Kislyakov, EF [1 ]
Sagaidak, DI [1 ]
Siaglo, AI [1 ]
Fedoruk, GG [1 ]
机构
[1] Belarusian State Univ, Minsk 220050, BELARUS
关键词
D O I
10.1134/1.1359818
中图分类号
O59 [应用物理学];
学科分类号
摘要
A model of the electron structure of a nanoobject comprising a stack of lead phthalocyanine (PbPc) molecules with stacking faults is proposed. The results of the molecular orbital (MO) calculation indicate that a 0.6e charge is transferred from Pb atom to the Pc macrocycle ring and show that the nanostructure can be considered as a metal-filled nanotube. The proposed model provides for the first time a quantitative interpretation of the electric switching effect previously observed in PbPc films. (C) 2001 MAIK "Nauka / Interperiodica".
引用
收藏
页码:180 / 182
页数:3
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