Synthesis and magnetic properties of novel polymeric complexes containing bithiazole rings

被引：6

作者：

Lin, Weihong ^{[1
]}

Sun, Weilin ^{[1
]}

Shen, Zhiquan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2007年 / 18卷 / 12期

关键词：

bithiazole; magnetic properties; FT-IR; transition metal chemistry; synthesis;

D O I：

10.1002/pat.882

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel linear polymer (PFABT) containing bithiazole rings was synthesized by polycondensation of 2,2 '-diamino-4,4 '-bithiazole (DABT) and formaldehyde. The complexes of PFABT with two transition metal ions (Fe2+, Cu2+) were prepared for the first time. The polymer was determined through FT-IR, H-1-NMR and elemental analysis (EA), and the complexes were characterized by FT-IR. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0-50 kOe) at 4 K and as a function of temperature (4-300 K) under an applied magnetic field of 30 kOe. The results show that PFABT-Cu2+ is a ferromagnet while PFABT-Fe2+ is an anti-ferromagnet. Copyright (c) 2007 John Wiley & Sons, Ltd.

引用

页码：959 / 962

页数：4

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