A novel one-dimensional coordination polymer involving weak Hg-Hg interactions

被引：40

作者：

Morsali, A

Kempe, R

机构：

[1] Tarbiat Modarres Univ, Sch Sci, Dept Chem, Tehran, Iran

[2] Univ Bayreuth, Lehrstuhl Organ Chem 2, D-95440 Bayreuth, Germany

来源：

HELVETICA CHIMICA ACTA | 2005年 / 88卷 / 08期

关键词：

D O I：

10.1002/hlca.200590160

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel, stable, one-dimensional coordination polymer [Hg-3(dmap)(6)(mu-OAc)(2)](n)[(ClO4)(4)](n) (1; dmap = 4-(dimethylamino)pyridine) has been synthesized and characterized. Single-crystal X-ray analysis showed that the coordination sphere of the two pertinent, zig-zag-oriented Hg-II-atoms is different. One type of Hg-atom in the N2O4Hg-HgN2O4 environment is seven-coordinate, with a weak Hg-Hg interaction. The other type of Hg-II-atom in the trans-HgN2O4 units is six-coordinate.

引用

页码：2267 / 2271

页数：5

共 20 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].