Central composite rotatable design for liquefaction of pine barks

被引:30
作者
Açikalin, K [1 ]
Karaca, F [1 ]
Bolat, E [1 ]
机构
[1] Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey
关键词
liquefaction; biomass; experimental design;
D O I
10.1016/j.fuproc.2005.04.005
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this study, the effects of various experimental parameters on the liquefaction yields of a biomass waste material, namely pine barks, were investigated statistically. The key parameters investigated were temperature, pressure, solvent to pine bark ratio and tetralin to solvent mixture ratio. A statistical experimental design based on second order central composite rotatable design was planned fixing the liquefaction period at I hour. The experimental design was done at five levels and the studied ranges for temperature, pressure, solvent to pine barks ratio and tetralin to solvent mixture ratio were 300-400 degrees C, 10-50 atm, 1/1-5/1 and 0/1-1/1, respectively. The effects of these factors on dependent variables, namely, oil+gas, asphaltene and preasphaltene yields and total conversion were studied in detail. To determine the significance of effects, the analysis of variance with 99.9% confidence limits was used. The model equations for dependent variables were also developed and an optimization study was done. (c) 2005 Published by Elsevier B.V.
引用
收藏
页码:17 / 24
页数:8
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