Diels-Alder reactions in chloroaluminate ionic liquids: Acceleration and selectivity enhancement

被引：208

作者：

Lee, CW ^{[1
]}

机构：

[1] Tennessee State Univ, Dept Chem, Nashville, TN 37209 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(99)00249-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The utility of room temperature chloroaluminate ionic liquids as solvent and catalyst for the synthetically important Diels-Alder reaction was studied. The AlCl3-1-ethyl-3-methyl-1H-imidazolium chloride medium proved to be ideally suited for Diels-Alder reactions. Endo selectivity and rate enhancement were observed for the cyclopentadiene/methyl acrylate Diels-Alder reaction. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2461 / 2464

页数：4

共 11 条

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