Polymer gel template for porous TiO2 production

被引:6
作者
Caruso, RA
Giersig, M
Willig, F
Antonietti, M
机构
[1] Max Planck Inst Colloids & Interfaces, D-14513 Teltow, Germany
[2] Hahn Meitner Inst, D-14109 Berlin, Germany
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1998年 / 102卷 / 11期
关键词
polymer gels; titanium dioxide; templating;
D O I
10.1002/bbpc.19981021105
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Porous networks of titanium dioxide have been produced using polymer gels as templates. Titanium dioxide is well known for its semiconductor and catalysis properties, and for being a very stable material. The porous polymer gels are produced in aqueous surfactant solutions. Following cleaning and solvent exchange procedures the titanium precursor can be incorporated within the gel and hydrolysed. The organic material is removed during calcination leaving the structured titanium dioxide. Both the rutile and anatase forms of titanium dioxide can be produced. The resulting crystal structure and the surface area of the oxide are important for determining its scope of application. These properties have been studied using electron microscopy, X-ray diffraction and gas sorption.
引用
收藏
页码:1540 / 1543
页数:4
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