The B1Π and C1Σ+ states of KLi

被引：27

作者：

Pashov, A

Jastrzebski, W

Kowalczyk, P

机构：

[1] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland

[2] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 292卷 / 4-6期

关键词：

D O I：

10.1016/S0009-2614(98)00702-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The polarization labelling spectroscopy technique is used to study the B (1)Pi <-- X (1)Sigma(+) and C C-1(+) <-- X (1)Sigma(+) band systems of the KLi molecule. Accurate molecular constants are derived for the B and C states from a Dunham expansion. For the B (1)Pi state our analysis covers more than 99% of the potential well depth and provides a precise value for its dissociation energy. This also allows dissociation energies of the ground X (1)Sigma(+) state and excited C (1)Sigma(+) state to be determined. (C) 1998 Elsevier Science B.V. All rights reserved.

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页码：615 / 620

页数：6

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