Preparation and properties of poly(methacrylamide)s containing oligoaniline side chains

被引：73

作者：

Chen, R ^{[1
]}

Benicewicz, BC ^{[1
]}

机构：

[1] Rensselaer Polytech Inst, Dept Chem, New York State Ctr Polymer Synth, Troy, NY 12180 USA

来源：

MACROMOLECULES | 2003年 / 36卷 / 17期

关键词：

D O I：

10.1021/ma030033+

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

New poly(methacrylamide)s containing oligoaniline side chains were synthesized and characterized. Oligoanilines were prepared by palladium-catalyzed amination, followed by reaction with methacryloyl chloride to give methacrylamide monomers. Polymers were prepared by free radical polymerization. The polymers were prepared in the leucoemeraldine state and were oxidized to the emeraldine state by exposure to oxygen gas. The electrochemical characterization of these polymers by cyclic voltammetry indicated that the redox behaviors were similar to the corresponding oligoanilines.

引用

页码：6333 / 6339

页数：7

共 26 条

[1]

[Anonymous], J POLYM SCI C

[2]

Chen R, 2003, ACS SYM SER, V843, P126

[3]

Spectroscopic and spectroelectrochemical properties of a poly(alkylthiophene)-oligoaniline hybrid polymer [J].

Dufour, B ;

Rannou, P ;

Travers, JP ;

Pron, A ;

Zagórska, M ;

Korc, G ;

Kulszewicz-Bajer, I ;

Quillard, S ;

Lefrant, S .

MACROMOLECULES, 2002, 35 (16) :6112-6120

[4]

Synthesis of a novel family of electrochemically-doped vinyl polymers containing pendant oligothiophenes and their electrical and electrochromic properties [J].

Imae, I ;

Nawa, K ;

Ohsedo, Y ;

Noma, N ;

Shirota, Y .

MACROMOLECULES, 1997, 30 (03) :380-386

[5]

NEW DIPHOSPHINE LIGANDS BASED ON HETEROCYCLIC AROMATICS INDUCING VERY HIGH REGIOSELECTIVITY IN RHODIUM-CATALYZED HYDROFORMYLATION - EFFECT OF THE BITE ANGLE [J].

KRANENBURG, M ;

VANDERBURGT, YEM ;

KAMER, PCJ ;

VANLEEUWEN, PWNM ;

GOUBITZ, K ;

FRAANJE, J .

ORGANOMETALLICS, 1995, 14 (06) :3081-3089

[6]

Syntheses of oligophenylenevinylenes-polyisoprene diblock copolymers and their microphase separation [J].

Li, WJ ;

Wang, HB ;

Yu, LP ;

Morkved, TL ;

Jaeger, HM .

MACROMOLECULES, 1999, 32 (09) :3034-3044

[7]

PHENYL-CAPPED OCTAANILINE (COA) - AN EXCELLENT MODEL FOR POLYANILINE [J].

LU, FL ;

WUDL, F ;

NOWAK, M ;

HEEGER, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (26) :8311-8313

[8]

Martin RE, 1999, ANGEW CHEM INT EDIT, V38, P1350, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1350::AID-ANIE1350>3.0.CO

[9]

2-6

[10]

SYNTHESIS OF A NOVEL TYPE OF ELECTROCHEMICALLY DOPED VINYL POLYMER CONTAINING PENDANT TERTHIOPHENE AND ITS ELECTRICAL AND ELECTROCHROMIC PROPERTIES [J].

NAWA, K ;

IMAE, I ;

NOMA, N ;

SHIROTA, Y .

MACROMOLECULES, 1995, 28 (03) :723-729

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