Plasma synthesis of ammonia with a microgap dielectric barrier discharge at ambient pressure

被引:122
作者
Bai, MD [1 ]
Zhang, ZT [1 ]
Bai, XY [1 ]
Bai, MD [1 ]
Ning, W [1 ]
机构
[1] Dalian Maritime Univ, Environm Engn Res Inst, Dalian 116026, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
ambient pressure; concentration of ammonia; dielectric barrier discharge (DBD); synthesis of ammonia;
D O I
10.1109/TPS.2003.818761
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The plasma synthesis of ammonia has been studied in nitrogen-hydrogen plasma using a microgap dielectric barrier-discharge at ambient pressure. With the new technology of dielectric layers, the high-energy electrons are obtained in a narrow discharge gap; meanwhile, N-2 and H-2 molecules are ionized and dissociated and a large number of free atoms, ions, and radicals are formed in a nonequilibrium plasma after inelastic collisions. The final product was mainly ammonia, and the yield of ammonia reaches 12500 ppm (1.25%). In this way, plasma synthesis of ammonia at ambient pressure is realized and a new method is provided for inorganic synthesis.
引用
收藏
页码:1285 / 1291
页数:7
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