Selective CO2 conversion to formate in water using a CZTS photocathode modified with a ruthenium complex polymer

被引：120

作者：

Arai, Takeo ^{[1
]}

Tajima, Shin ^{[1
]}

Sato, Shunsuke ^{[1
]}

Uemura, Keiko ^{[1
]}

Morikawa, Takeshi ^{[1
]}

Kajino, Tsutomu ^{[1
]}

机构：

[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 47期

关键词：

SEMICONDUCTOR PHOTOCATALYSIS; THIN-FILMS; PHOTOREDUCTION; REDUCTION; ZNS; NANOCRYSTALLITES; CADMIUM; SULFIDE; ZINC;

D O I：

10.1039/c1cc16160a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly selective photoelectrochemical CO2 reduction (> 80% selectivity) in water was successfully achieved by combining Cu2ZnSnS4 (CZTS) with a metal-complex electrocatalyst. CZTS, a sulfide semiconductor that possesses a narrow band gap and consists of earth-abundant elements, is demonstrated to be a candidate photoabsorber for a CO2 reduction hybrid photocatalyst.

引用

页码：12664 / 12666

页数：3

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