Facile means of preparing superamphiphobic surfaces on common engineering metals

被引:170
作者
Meng, Haifeng [1 ]
Wang, Shutao [2 ]
Xi, Jinming [1 ]
Tang, Zhiyong [1 ]
Jiang, Lei [1 ,2 ]
机构
[1] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China
关键词
D O I
10.1021/jp803027w
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work, orienting to practicality and functionality beyond original fundamental simulation, we succeeded in fabricating superamphiphobic surfaces, which are super-repellent both to water and oil, upon common engineering metals (zinc, aluminum, iron, and nickel) and their alloys (Zn-Fe alloy and brass) by taking advantage of an electrochemical reaction in perfluorocarboxylic acid solutions. Via control over the chain length, concentration of perfluorocarboxylic acid, and the process time, textured rough structures on different substrates were achieved. The prepared surfaces show superamphiphobicity due to the synergistic effect of their special surface compositions and microscopic structures.
引用
收藏
页码:11454 / 11458
页数:5
相关论文
共 46 条
[1]  
ADAMSON AW, 1990, PHYS CHEM SURFACES, P400
[2]   Adhesive force of a single gecko foot-hair [J].
Autumn, K ;
Liang, YA ;
Hsieh, ST ;
Zesch, W ;
Chan, WP ;
Kenny, TW ;
Fearing, R ;
Full, RJ .
NATURE, 2000, 405 (6787) :681-+
[3]   Engineering - Shark skin and other solutions [J].
Ball, P .
NATURE, 1999, 400 (6744) :507-+
[4]   Purity of the sacred lotus, or escape from contamination in biological surfaces [J].
Barthlott, W ;
Neinhuis, C .
PLANTA, 1997, 202 (01) :1-8
[5]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[6]   Ultrahydrophobic and ultralyophobic surfaces:: Some comments and examples [J].
Chen, W ;
Fadeev, AY ;
Hsieh, MC ;
Öner, D ;
Youngblood, J ;
McCarthy, TJ .
LANGMUIR, 1999, 15 (10) :3395-3399
[7]   Super-repellent composite fluoropolymer surfaces [J].
Coulson, SR ;
Woodward, I ;
Badyal, JPS ;
Brewer, SA ;
Willis, C .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (37) :8836-8840
[8]   Super-hydrophobic surfaces: From natural to artificial [J].
Feng, L ;
Li, SH ;
Li, YS ;
Li, HJ ;
Zhang, LJ ;
Zhai, J ;
Song, YL ;
Liu, BQ ;
Jiang, L ;
Zhu, DB .
ADVANCED MATERIALS, 2002, 14 (24) :1857-1860
[9]   Design and creation of superwetting/antiwetting surfaces [J].
Feng, Xinjian ;
Jiang, Lei .
ADVANCED MATERIALS, 2006, 18 (23) :3063-3078
[10]   A perfectly hydrophobic surface (θA/θR=180°/180°) [J].
Gao, Lichao ;
McCarthy, Thomas J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (28) :9052-9053