Oxidation of galactose and derivatives catalysed by galactose oxidase: structure and complete assignments of the NMR spectra of the main product

被引：16

作者：

Bonnet, V

Duval, R

Rabiller, C

机构：

[1] Fac Sci & Tech, Unite Rech Biocatalyse, FRE CNRS 2230, F-44322 Nantes 3, France

[2] CHIRALSEP, La Fresnaye, France

来源：

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2003年 / 24-5卷

关键词：

galactose oxidase; hydrates of 6-oxogalactosides; NMR parameters;

D O I：

10.1016/S1381-1177(03)00065-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This paper deals with the analysis of the structure of 6-oxogalactose and 6-oxogalactosides obtained from the oxidation reaction catalysed by galactose oxidase. A complete analysis of the H-1 and C-13 NMR spectra showed that 6-oxogalactose and 6-oxogalactosides were mainly present as the hydrate of the monomeric form. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：9 / 16

页数：8

共 14 条

[1]

AVIGAD G, 1962, J BIOL CHEM, V237, P2736

[2] C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF MONOSACCHARIDES [J].