Upper bound and best estimate of the efficiency of the iodine sulphur cycle

被引：164

作者：

Goldstein, S ^{[1
]}

Borgard, JM ^{[1
]}

Vitart, X ^{[1
]}

机构：

[1] CEN, CEA, DEN, DPC, F-91191 Gif Sur Yvette, France

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2005年 / 30卷 / 06期

关键词：

reaction; thermodynamic data; efficiency;

D O I：

10.1016/j.ijhydene.2004.06.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An upper bound and a best estimate of the efficiency of a thermochemical iodine sulphur water splitting cycle coupled with a High Temperature Reactor operating between 760 K and 1144 K are proposed in this publication. An upper bound of 51% is found assuming ideal reversible chemical reactions and constraints related to the heat exchange between helium and chemical process. It appears that the separations between water and sulphuric acid on one hand and water, HI and iodine on the other hand are the most energy consuming. The best estimate of the efficiency is found between 33% and 36% according to the assumptions made for the temperature pinch at the heat exchangers of the hydrogen production section. More realistic values can be obtained after having designed the heat exchangers of this section. (c) 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：619 / 626

页数：8

共 17 条

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Barin I., THERMODYNAMIC PROPER

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