Benchmark values for the Soret, thermal diffusion and diffusion coefficients of three binary organic liquid mixtures

被引:141
作者
Platten, JK
Bou-Ali, MM
Costesèque, P
Dutrieux, JF
Köhler, W
Leppla, C
Wiegand, S
Wittko, G
机构
[1] Univ Mons Hainaut, Gen Chem Serv, B-7000 Mons, Belgium
[2] Univ Basque Country, Dept Fis Appicada 2, E-48080 Bilbao, Spain
[3] Univ Toulouse 3, Lab Mecan Transfert Geol, F-31000 Toulouse, France
[4] Univ Bayreuth, Inst Phys, D-95440 Bayreuth, Germany
[5] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
D O I
10.1080/0141861031000108204
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
With the aim of providing reliable benchmark values, we have measured the Soret, diffusion and thermal diffusion coefficients of the three binary mixtures of dodecane, isobutylbenzene and 1,2,3,4 tetrahydronaphthalene for a concentration of 50 wt% at a temperature of 25degreesC. The experimental techniques applied by the five participating laboratories are transient holographic gratings, annular and parallelepipedic thermogravitational columns, and vertical parallelepipedic columns with velocity amplitude determination by laser doppler velocimetry. The systems have also been studied in a annular thermogravitational column filled with a porous medium in the gap. There is a good agreement between the different experiments with deviations of the order of a few per cent in most cases (8.5% at most). The numerical values are tabulated in the paper.
引用
收藏
页码:1965 / 1971
页数:7
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