Multinuclear NMR spectroscopic characterization of vanadium(V) alkylperoxo complexes VO(OOtBu)k(OnBu)3-k, where k=1, 2, 3

被引：11

作者：

Babushkin, DE ^{[1
]}

Talsi, EP ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 71卷 / 01期

关键词：

mechanism; oxidation; alkylperoxo complexes; vanadium; NMR spectroscopy;

D O I：

10.1023/A:1010394401961

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using V-51, O-17, C-13, and H-1 NMR spectroscopy, vanadium(V) alkylperoxo complexes VO(OOtBu)(k)(OnBu)(3-k), where k = 1, 2 and 3, were characterized in the reaction of VO(OnBu)(3) with tBuOOH in CH2Cl2.

引用

页码：115 / 120

页数：6

共 11 条

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