On the use of removable steric buttresses in cycloaddition reactions

被引：35

作者：

Choony, N ^{[1
]}

Dadabhoy, A ^{[1
]}

Sammes, PG ^{[1
]}

机构：

[1] Univ Surrey, Sch Phys Sci, Dept Chem, Mol Probes Unit, Guildford GU2 5XH, Surrey, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 13期

关键词：

D O I：

10.1039/a802415d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Use of bulky protecting groups, such as the trityl group, can be utilised to encourage cycloaddition reactions that otherwise do not proceed. Thus N-allylfurfurylamines, bearing the appropriate N-protecting group, can thermally cyclise; subsequent removal of the protecting group produces the thermodynamically unstable, free amine.

引用

页码：2017 / 2021

页数：5

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